The Avengers - Season 2 Episode 23 - New Avengers
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Kang the Conqueror is freed from prison by his alternate timeline doppelgangers and attempts to conquer the world once again, this time trapping the Avengers in a temporal void to keep them from getting in the way of his plans. Now a new team of heroes (Spider-Man, War Machine, Wolverine, Iron Fist, Luke Cage, and the Thing) must band together to stop the cross-temporal onslaught.